Synthetic Tannins

Georg Grasser

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• Publié par: thiwyang
• Publié le: 08 décembre 2010
• Nombre de lectures: 73
• Langue: English

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**Welcome To The World of Free Plain Vanilla Electronic Texts** **eBooks Readable By Both Humans and By Computers, Since 1971** *****These eBooks Were Prepared By Thousands of Volunteers!*****

*** START OF THE PROJECT GUTENBERG EBOOK SYNTHETIC TANNINS ***

Title: Synthetic Tannins Author: Georg Grasser Release Date: April, 2005 [EBook #7981] [Yes, we are more than one year ahead of schedule] [This file was first posted on June 8, 2003] Edition: 10 Language: English

SYNTHETIC TANNINS THEIR SYNTHESIS, INDUSTRIAL PRODUCTION AND APPLICATION

Produced by Juliet Sutherland, Thomas Hutchinson, Charles Franks and the Online Distributed Proofreading Team.

by Georg Crasser, Dr. Phil., Ing. Lecturer in Tanning Chemistry at the German Technical College, Brunn

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s.tac innnehitystnht eo  ftionoduce pre thlbissop

GRAZ, August  

The intention of the present volume is to communicate to the reader what has so far been scientifically evolved and practically applied in this field. First of all, however, it may illustrate the extreme importance and the universal applicability of the synthetic tannins in the making of leather. The modern leather industry cannot, to-day, be without these important products, but also in those tanneries, where the synthetic tannins have not so far been regarded as indispensable, their use is strongly recommended. Just as in the case of the coal-tar dyes, the synthetic tannins will make us independent of foreign supplies, and thus keep within our own borders the vast sum of money required in former days for the purchase of foreign tanning materials. May this book prove the means of providing an incentive for a still wider application of the synthetic tannins.

GRASSER.

129.0

The scientific results of Fischer's researches are to-day common knowledge, and these, together with questions arising therefrom, will only be lightly touched upon in the book herewith presented. Even an attempt at enumerating the present synthetic tannins has so far not been published, and I have therefore availed myself of the opportunity of making a brief summary of them. My work at the B.A.S.F. deepened my insight in this new field; ample opportunity of applying these synthetic products in practice was given me when, as a result of the war, I was appointed technical consultant to the Austrian Hide and Leather Commission, and in this capacity was called upon to act as general adviser to the trade. The ultimate object of my scientific researches was then to investigate the chemistry of this particular field, and this has led me to present a picture, complete as far as it goes, of this branch of chemical technology.

TRANSLATOR'S PREFACE

Doctor Grasser hardly needs an introduction to the leather trade of this country in its scientific aspect, but if one be sought for, none could serve the purpose better than a translation of the book herewith presented to the British-speaking public. Viewed with curiosity from their start, the synthetic tannins needed—like many other important discoveries—an extreme emergency for the purpose of showing their value. The Great War provided the opportunity of which chemical industry was to avail itself, and to-day we do not only see synthetic tannins placed upon the market as a veritable triumph of chemical technology and a creditable triumph of manufacturing chemistry; we also see their immensely practical qualities established as a fact, and, as the author aptly remarks, no modern tanner can to-day dissociate himself from the use of synthetic tannins for the production of leather in the true sense of this word. There is no branch of leather-making where synthetic tannins cannot help and improve processes already established. The immense number of substances patented by German manufacturing chemists for the purpose of producing synthetic tanning materials is almost staggering. In view of this fact it is doubly pleasing to see that British chemists have found new ways, and are able to produce equally good and more varied synthetic tannins than has hitherto been deemed possible. The originator of these products and his acolytes must at least share the credit with those who, in spite of the limitations necessarily set by the former, have been able to find new and better ways. In his book Dr. Grasser gives a short review of the necessary forerunner of any work upon synthetic tannins: the investigations and syntheses of the natural tannins. It is certainly to be hoped that we may soon see such works as those of Fischer's and Freudenberg's, recently published, translated into English. For the guidance of the reader it may be noted that a short account of the works of these authors may be found in the Journal of the Society of Leather Trades' Chemists addition to this some of the matter contained in the chapter on synthesis of tanning, vol. v. (May issue); in matters appeared in the January 1921 issue of the Journal of the American Leather Chemists' Association. In addition to these two sections, the last part of this book deals with the practical applications of synthetic tannins, and it is hoped that the tanner will find much valuable information in these pages. The main outlines of the synthesis of tanning matters should prove of great value to the chemist engaged in this branch of chemical technology. The translator takes great pleasure in the acknowledging the valuable assistance rendered him by Mr. Robin Bruce Croad, A.R.T.C., F.I.C., and by Mr. Arthur Harvey.

F. G. A. ENNA

arepPr     s   desi edarteT fo noita anno   T es    psid  sfonaecbutsdiS    n S   n n e i u p t e o T l y n h   e i   o t   a B n o   f T l s e   k t a r   i e w t o i h     d   n   a   a a N h   C     t e u c r o a m l p   o T s a i n n n g i   n t s he

SECTION II

 

Synthesis of Tanning Matters 1. Aromatic Sulphonic Acids 2. Condensation of Phenols  Condensation of Hydroxybenzene  Condensation of Dihydroxybenzene  Trihydroxy benzene  Polyhydroxybenzenes  Quinone  Phenolic Ethers  Nitro Bodies  Amino Bodies  Aromatic Alcohols  Aromatic Acids 3. Condensation of Naphthalene Derivatives 4. Condensation of the Anthracene Group 5. Di- and Triphenylmethane Groups 6. Summary Table

D

SECTION IV

r

SECTION III Tanning Effects of Mixtures and Natural Products 1. Mixture of Phenolsulphonic Acid and Formaldehyde 2. Mixture of Phenolsulphonic Acid and Natural Tannins 3. Tanning Effects of Different Natural Substances

Pd

Methods of Examining Tanning Matters

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ombination Tannaeg siwhtN redalo  oesNef doraD l nnaT   ega     C .8 tingstra       the aVir    tSgauo s ea R7.  sus ntgef elbatinomeD ro  l DaTnn teNarod 9. Analy age       reN lodastladna  (3  Fa)                   ousrL qi um Sumin) Al  (2  )1(           D   Dolader NmeroCh morfluS ruhpA ciraNel do FD,e re arod l   D     11 . r Tanned with Neo seitreehtaeL f     D   l  opPr. 10 nininoatarod geNof Lsis er ceath nd Ieducsaenonti .1 dnoC dicA      lphonic Phenolsu det    o    saA ppiln ioatnsdeon Cof sdohteM tnereff. Di dol G Neraral eNtu21 .     ic   d    )D lodareN( di D l doraNe.  1     .2  s    itnoeRca mica-Chectro Ele ysmlteah.FD cierhonic Acnedisulp ehT not gnE nain entsCont          4      D  abolhP . oft ecffolader N redaloD      3  . l Behaviour of N laS a stA dn dice ThflInncueofe   Ners oftionReac6  .     ePtlo  n    s   ieallk And anorI htiw D loda n of Nerng Actioulibilishpne eoS ader Dolt ec Nof.5  ffE  loda     s     .  2 y  batHe noittiw dnoCasner Chlorih Sulphu  .oCdnne ed     3 osPhh it wontisasdnuopmoC surohp ensaCond 4.     edyh hlAw tiitno   sed     C .5ednoatnsn iothwily Gecorl

REGISTER OF AUTHORS

INDEX

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INTRODUCTION CLASSIFICATION OF SYNTHETIC TANNINS

 swelling it. A ohti ,tuewoh,revenrdths hie  wde  animal ardeningso efoh ht eupprk orr foicog walih nlotsyolpi de t haby ihereon wulit mosf orbrdesoaby iladres  iti hcihw yb ,edih