Transmission electron microscopic investigations of heteroepitaxial III/V semiconductor thin layer and quantum well structures [Elektronische Ressource] / vorgelegt von Igor Németh
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Transmission electron microscopic investigations of heteroepitaxial III/V semiconductor thin layer and quantum well structures [Elektronische Ressource] / vorgelegt von Igor Németh

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olfenTPhilipps-Univransmissionacelectrongmicroscopicrer.inhvoestigationsIgorofhaftenheterodemepitaxialbIysikIMarburgI/Vgelsemiconductorvthinausla(Lahn)y(Dr.ernat)andFquanhtumereicwPhellderstructuresersit?tDISSERvTrAeTIONtzuronErlangungN?methdesWDoktorgradesMarburgder2008NaturwissensceitgutacVPD.omTFVacDr.h?ndlicbhabil.ereiclzhter:PhhysikderderPr?fung:PhiliDr.pps-UnivKerstinersit?toMarburgZwalshDissertationProf.angenommenUlricam:H?fer11.03.2008agErstgutacmhhente18.03.2008r:grLoundondonUnder.Con.ten.ts.List.ofDarkT.ables.7.List.of3.3.1.Figures.8.1..InbuertroSiduct34ion.1.2..F.undamen.t.als.5.2.1.dsCrystal.structurepretreatmen...............Mi...di.T...microscop.........eld.........3.1.1........3.1.2.......5.2.2..Challenges.of.Hetero.epitaxy..............tomi.......High.....APD.....3.3...............5comp2.2.1..Charge.neutralittiphasey.of5the.hete.roi.n.terface......wth...............Substrate......6.2.2.2..An3.1.3.tiphasewthdisorder............34.................Structural...............3.2.1..F.roscop7.2.2.3..Othe.r.planar.defects:39stacX-Rakingractionfaults,.microt.wins41.hniques.ti...........ransmission..11.2.2.4..Lattice.mismatc.h.-FieldRelaxation............46.TEM.anal.......3.3.3..of............12.2.2.5..Dier.ence.in.thermal.expansion.co.ecien.ts......32.Gro.metho..............13.2.2.6..In.terdiusion......32.Si.and.t...................33.Si.gro....................14.2.3..Theory.of.elec3.1.4.tronsurfacediraction..............................3.2..analysis......

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Publié par
Publié le 01 janvier 2008
Nombre de lectures 14
Poids de l'ouvrage 11 Mo

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olfenTPhilipps-Univransmissionacelectrongmicroscopicrer.inhvoestigationsIgorofhaftenheterodemepitaxialbIysikIMarburgI/Vgelsemiconductorvthinausla(Lahn)y(Dr.ernat)andFquanhtumereicwPhellderstructuresersit?tDISSERvTrAeTIONtzuronErlangungN?methdesWDoktorgradesMarburgder2008NaturwissensceitgutacVPD.omTFVacDr.h?ndlicbhabil.ereiclzhter:PhhysikderderPr?fung:PhiliDr.pps-UnivKerstinersit?toMarburgZwalshDissertationProf.angenommenUlricam:H?fer11.03.2008agErstgutacmhhente18.03.2008r:grLoundondonUnder.Con.ten.ts.List.ofDarkT.ables.7.List.of3.3.1.Figures.8.1..InbuertroSiduct34ion.1.2..F.undamen.t.als.5.2.1.dsCrystal.structurepretreatmen...............Mi...di.T...microscop.........eld.........3.1.1........3.1.2.......5.2.2..Challenges.of.Hetero.epitaxy..............tomi.......High.....APD.....3.3...............5comp2.2.1..Charge.neutralittiphasey.of5the.hete.roi.n.terface......wth...............Substrate......6.2.2.2..An3.1.3.tiphasewthdisorder............34.................Structural...............3.2.1..F.roscop7.2.2.3..Othe.r.planar.defects:39stacX-Rakingractionfaults,.microt.wins41.hniques.ti...........ransmission..11.2.2.4..Lattice.mismatc.h.-FieldRelaxation............46.TEM.anal.......3.3.3..of............12.2.2.5..Dier.ence.in.thermal.expansion.co.ecien.ts......32.Gro.metho..............13.2.2.6..In.terdiusion......32.Si.and.t...................33.Si.gro....................14.2.3..Theory.of.elec3.1.4.tronsurfacediraction..............................3.2..analysis..............14.2.4..Rened.structure.factor.c.al.c39ulAationc.orce.c.y.......................3.2.2..Resolution.y..(HRXRD)..27.2.4.1..V.alence.F3.2.3.orceecFieldfor(VFF)detec.on...................44.T.electron.y..............28.2.4.2..De.nsi45tDarkyTEMF.unctional.Theory.(DFT)....................3.3.2..eld.for.osition.ysis......29.3..Exp.erimen47talDarkMeimagingthanodomainsds.32.3.1..Crystal.gro.wth..48...Con.tenonsts.3.3.4..Con.v.ergeneent.bDetectioneam.electronhdiraction.(CBED)........tin.....menfassung......57.3.3.5..P.ol.arit{111}y.sensitiv.e.b.endtcon.toursharge.and.....of...vi...........samples...of.......stoic64.3.3.6..Dete5.2.2.ction.of.otherCorrelationplanarSidefects..Annihilation.......5.5..surface.....y...5.5.2........of....67and3.3.7..High-resolutionaryTEMendix.........TEM.......sec.....139.......The...............5.2.1.70{110}4..Quan.titativ.e.comp.ositionalnon-stoicanalysis.of.QW.s.b103yetDFTEMstructure80.4.1..Rened.structure104factorAPDscalculati.on.with.VFF.and.DFT....p.and.construction.......5.5.1..rst80-4.2.yGa(NAs)/GaAs....wth.olarit.........119.ev.planar.......5.7..n.wth.....6..7..A..A.1..................13884preparation4.3..Ga(NAs)/GaP..........A.2.1..on...........Plan.............143.structure.APBs......................85.4.4..Ga(P101As)/GaPThe.hiometric.APB...................101.The.hiometric.APB.................5.3..b.w.APD.and.surface......87.4.5..(BGa)P/GaP..5.4..of.............................109.Crystal.olari.y.Si.re...............115.Discon.uous89monola4.6.erGa(NP)/GaPc.neutralit.........116.Gro.conditions.p.y...................5.6..and.olution.other.defects.............121.Summary91optimized4.7.ucleationGa(AsSb)/GaAsgro.conditi.........130.Summ.132.Zusam.135.App.138.Abbre.ations................................92A.2.5.sampleHetero.epitaxy.and.defect.c.haracterization.(GaP.on.Si).94.5.1..Nucleation.of.GaP139onCrossSiti.sandwic.samples...................A.2.2..View..........................9465.2..List4.2.of.Taablesrs2.1..ThermalaroundexpansionVFFcoolaritecien.tsbof.semiconductorsn.iso-.d.....GaP.conditions...ate.DFT.....of13ond2.2.solatedVFFimpuritiesparameterslofDFTbinary.comp.ounds..5.1..of.y.gro.......7.d.y.........81.Strain.anion-catio.b29lengths3.1.iConsubstitutionaltrastelectricrulescforlcudynamicalateBragg-linesusingiandn.002.CBED.discs......81.P.y.the60la4.1.eKinematicand(002)wthelectr.o.n.form.factors.c.al120culGa(N As )x 1−x
002
{111} {111}
Blo.....(AFM)...t5.2.2.diractogramCrystal.p.olari.t.y.ofloGaPHRXRD...Reection...thic...cell.an.........3.3..Assem...quan.er.Crystal.of.sample.....reections.b...dark.of..7.2.3.nsOriginnon-pof020ancontiphase.b.oundaries.in.zinc.-.bleofndesystemstructureatomic.....a.structure.GaP.Si...an.a8tensit2.4.GaPAnzonetiphase.disorder.on.dieren.ttensitiesplanesersuof3.10.thethez.i.ncinblendeGaPstructureDark.wi.(b)..8.2.5.DarkFdierenalse.bviewondctionconguration56ofofthenueself.annihil.ating.{111}.APBs7............9.2.6..StacdimerkingSi-surfacefaults,comi38cofrotmicroscopwins.in.zincblende.crystal40.o.m.w.3.6..f.la.wn.....43.del.PB.h12e2.7.002Scattering49oftensitiesaersusplaneknesswexcitationa.v.e.on.a.single.atom....3.9..the.GaP.the...observ.002/...........3.11..of16images2.8.tiphaseScattering53onimageatakunit(a)cell2.1..of.........54.images.domains.reec...3.14..of.along.[001].....Plan.eld.in.tilt.on..........17.2.9..Ew.ald.construction................................37.Surface.structure.the.and.cal.ordinate...3.4..bly.the.force.e..19.2.10..N-con.ten.t.dep.endence3.5.odiractogramfftheGa(NAs)/GaPstructureultifactortumofell.42.HRXRD.o.a.thin.y.grostructureonzincblende..........3.7.22mo2.11.ofTheAcompforonenctswofvthecalculationincidenthetinandyscattered3.8.winaofvvethevthicectorinataxisthe.crystal.surface..............................50.In.of.{002}.of.v.s.sample.kness.51.APDs.ed.y.diamond.DFTEM..............23.2.12..Beam51pathImageintensitiesTEM111.eld.of.an.domains...3.12..eldandpairreectionAPDs.en.th.of.Unit.and.Figures.List......................................3.13..eld.of.tiphase25using3.1.tDerivtioativ.e.AFM55imageUniofcellaGaPKOH-etcedhedtheSiolar(001)direw.afer......3.15..view.dark.images.APDs.GaP.The35i3.2.nceEecttheoftrastthe.lo.cal.misorien.ta.t.i.on.and.annealing.on.the.Si.surface.step.structure..5.8.1
111
.3.16..Beamratiospath.in.conRolevers:enmeasuredtional.diractionmicrographsawthnd.inofCBED......dark.......eld.94...the..58des3.17..Excitati.onwithconditions.andnormal-scattering.paths.forwpeldolarit(BGa)P/GaPymeasuredetermination.in.CBEDand.Cal...uous.GaP.....AFM.y.....t.TEM.....5.6....of.del...86.in...........Ga(P...and.ratios.dark.ells.90.y..614.9.3.18.tumP.olaritcy002d.eterminatiodnyinIllustration[1conofde0]HRGaPywithmonolaCBED........imag.GaP...........sequence.e.5.5.62n3.19.GaPP.olarit.y.analysis.withofCBED.in.GaP5.7.anannihilatingtiphaseanddomains........Calculated.eld.of.to..63.3.20..Origi.n.of.b.end.con4.5.toursmicrographs.quan.....4.6..d.tensit.Ga(P.4.7..micrographs.tum.....Calculated.in.of.......dark.Ga(NP).ells.....4.10..ate.dark65tensit3.21.Ga(NP)Bend92conultourmeasuredanalysisinonofan93tiphasethepatternedof[001]iGaPwth...AFM.images.ucleation.on.the.er..66.3.22..Dark.eld.imaging.of.microt96winsHRinscrosseectsectionucleation.on.................5.4..gro.the.uc68on3.23..Conandtrastoforiginlaofofstacwthking.f.aults.and.microt.wins......TEM.{110}...........eld.l.s691113.24.geometricalH.R.TEM.image.sim.ulation9pro.cess..4.4..and.dark.002.tensities.Ga(NAs).ized.GaP..........................73.3.25..Si.m87ulated002high-resolutioneldTEMofimaAs)/GaPgetumsellsof.{110}.APBs.in88GaPCalculated.measure.dark.in.y.of77As)/GaP3.26.89Si002meldulatedofhigh-resolutionquanTEMwimages.of.{111}.APBs.in4.8.GaPandwithdGatensit-ratiosGa(BGa)Pfalse.b.onds......90.002.eld.of.quan.w...........91.Cal.ul.d.measured.eld.in.y.of.....4.11..c.ate.and.dark70028tensit3.27.ratiosSiGa(AsSb)m.ulated5.1.high-resolutionofTEMgroimagessequenceofthe{111}tAPBsningroGaPmowith.P.-5.2.PandfalseTEMbofondsn.la.ers.Si..of.rst.y.................................5.3..and.TEM.e.of.annealing.of.n79la4.1.ersStaticSiatomic.displacemen.t............................98.Illustration.the.wth.of.dieren.n.l.ati.mo...9882AFM4.2.HRCalculatedimagesandGaPmeasureducleationdarkyeldRole002theingrotensitiessequenceof.Ga(NAs).normal-.ized.to.GaAs....................100.HR.micrograph.a.APB....................102.Dark.images.se.f.APD.made.theListandFigures.reections8a5mo4.3..002.dark.eld.micrographs.of.Ga(NAs)/GaP.quan.tum.w.ells103...Listofof.Figuresucleated5.8.ICorrelationwithbphaseet.wpeen.Si131surface.step.morphology.and.thesectionallateral.pattern-125ingTEMofeAPDs.in.GaP....I.p...HR.....AFM.n...w...stac...y.e...5.25....mple.Cr.A.3........T.the..1y05.5.9..DarkAFMeldhigh002GaPmicrographs.of.the.annealing.eecplantGaPoncomthe.surface.of5.21.{110}kiAPD.patterned.GaPet.and.....APB.fault...e.......optimized.....ss.-holder...TEM.ining.sample...........5.17.106smal5.10.eAFMformedandterracesplan.view5.18.DFTEMymicrographofof.lo.w-te.mp.erature120groDFTEMwnimagesGaPeraturelagroy.er.on.the.optimized.Si.surface....122.dark.and.of.y.with.sc...........b.en.faults.y..109.5.11..CrossCorrelationsectionale002ngdarkolariteld.micrograph.of.a5.23.GaPoflatersectedystacer.sho.wing5.24.TheypGaPeyI.and.T.yp.e.IimagesInAPDs........Cr.TEM.with.....140.ss.mple.-sust...view...........143...........117.Origin.the110l5.12.ypAFMIandAPDsDFTEMonimagesSiof.high.temp.erature119groGaPwnolaritGaPbladominationyoneers.with.kinking.T.yp.e.I.APDs....5.19..,.and.TEM.of.temp.n.and.wn...................................5.20.1and11eld5.13.viewAFMcrossandstudyDFTEMaimageslaoferselfucleatedannihilationtheofbinedAPDshemein.GaP.at.high.temp.erature.gro.wth.and.using124optimizedCorrelationSietsurfacee.stac.ng.and.olarit.I...........113.5.14.5.22.ShapbewofenthekiselffaultsannihilatingpTyypI.e.I.APDs.on.plan.view126DFTEMHRim-imageagesanandinonbaageometricalkingmo.del......128.Tim.sc.m.of.hetero.pitax.....................131.TEM.of114GaP5.15.ucleationLo.cal.co.ordinate.system.and.GaP.p.olaritA.1.yo.sectional.sa.preparation.Ti...........A.2..o.sectional.sa.preparation.self.a116samples5.16.142PPlanolaritTEMypreparationanal.ysis.of.a.single-domain.GaP.la.y.er....10.

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