227 pages

Vectorial properties and laser control of molecular dynamics [Elektronische Ressource] / vorgelegt von Philipp Marquetand

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HeidelbVW?rzburgectoDoktorgradesrialonphaftlicropJulius-Maximilians-UnivertiesorgelegtandMarquetandlaserW?rzburg,controlhenofdermoleculaersit?trvdynamicsvDissertationPhilippzurausErlangungergdes2007naturwissensc.Eingereic.h.t.am:......ag.............des...................Pr?fer:.........Promotionsk.hen.....am:......b.ei.der2.F.akult?t.f?r.Chemie.und.Pharmazie.1..Gutac.h.ter:..................tlic.quiums.?en.ollo.........Doktorurkunde.........................Pr?fer:......2..Gutac.h.ter:......................3......................................?en.hen.ollo.TderdesDissertationtlic1.PromotionskPr?fer:quiums:...................ausgeh?ndigt..........................Contentstheory1.Intro.duction.1.231Basic.p.rinciples.5.2.1.Classical.dynamics..32.Relaxation.The...2.5.1...............................36...........Diabatic5.2.2.Quan.tum.dynamics............3.for...3.2.......tec...............freedom.....tegral......7.2.3diabaticProp.erties.of.electro-magnetic.elds..26.............2.5.3...............2.6....11.2.3.1.Chirp.and.F.ourierMethotransformRunge-Kutta.tra.......propagator.............Split-op............13322.4dIn.teraction.of.electro-magnetic.elds.with.matter34.degree...........Simpson......18.2.4.1.Time-dep.enden.t.p25erturbationAtheoryexpansion.......................2.5.2.expansion19.2.4.2.F.ermi's.golden.rule............27.Example.............................28.Landau-Zener20.2.4.3.Rotating.w.a.v.e.appro.ximation..........29.Numerical.ds.3.1.algorithm.

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Publié par
Publié le 01 janvier 2007
Nombre de lectures 12
Poids de l'ouvrage 9 Mo

HeidelbVW?rzburgectoDoktorgradesrialonphaftlicropJulius-Maximilians-UnivertiesorgelegtandMarquetandlaserW?rzburg,controlhenofdermoleculaersit?trvdynamicsvDissertationPhilippzurausErlangungergdes2007naturwissensc.Eingereic.h.t.am:......ag.............des...................Pr?fer:.........Promotionsk.hen.....am:......b.ei.der2.F.akult?t.f?r.Chemie.und.Pharmazie.1..Gutac.h.ter:..................tlic.quiums.?en.ollo.........Doktorurkunde.........................Pr?fer:......2..Gutac.h.ter:......................3......................................?en.hen.ollo.TderdesDissertationtlic1.PromotionskPr?fer:quiums:...................ausgeh?ndigt..........................Contentstheory1.Intro.duction.1.231Basic.p.rinciples.5.2.1.Classical.dynamics..32.Relaxation.The...2.5.1...............................36...........Diabatic5.2.2.Quan.tum.dynamics............3.for...3.2.......tec...............freedom.....tegral......7.2.3diabaticProp.erties.of.electro-magnetic.elds..26.............2.5.3...............2.6....11.2.3.1.Chirp.and.F.ourierMethotransformRunge-Kutta.tra.......propagator.............Split-op............13322.4dIn.teraction.of.electro-magnetic.elds.with.matter34.degree...........Simpson......18.2.4.1.Time-dep.enden.t.p25erturbationAtheoryexpansion.......................2.5.2.expansion19.2.4.2.F.ermi's.golden.rule............27.Example.............................28.Landau-Zener20.2.4.3.Rotating.w.a.v.e.appro.ximation..........29.Numerical.ds.3.1.algorithm.classical.jectories...........3122Short-time2.4.4.Rabi.oscillations......................3.3.erator.hnique........................233.42.5methoA.diabatic.vs..diabatic.p.oten.tials.and.Born-Opp.enheimer.appro.xi-.mation....3.5.rotational.of.....................3.6.in.............................38.+ −
.Contents.4.Control.theo.ries.-.A.sho.rt.overview.39LCT4.1.Brumer-Shapiro.quan.tum.in65terference..dynamics.mo.............111.oling...Disso...I.....6.339.4.2VSTIRAPin.........88...sp.....7.2.1.....100.7.3...............ciation.....+.......ciation.....of..40.4.3.Tropannor-K81oslo-Riceeldpump-dump..........P.......dynamics.....90.......degree......41.4.4.Chirping100.....in...y...........6.1.2...............61.and...........6.2.1.vs..I..........42Suppressing4.5.Genetic.algorithms.and.feedbac.kconcon.trol..........72.rial.ro-vib.external.Predisso.static.........7.1.142system4.6.Optimal.con.trol.theory..82.states.............Quan.............Pump-prob.y.........96.the.freedom..44.4.7.Lo.caloriencon.trol.theory.(LCT)......Rotational-vibrational.........Rotational-vibrational.static.....p.orien..................46.557LoCocal.control.theo.ry.revisited.47.5.1.Energy.ob.jectiv.e..........6.2.ciation.Predisso.....................63.Na.I.Na.+I.............48.5.2.Vibrational.eigenstate.ob.jectiv6.2.2epredisso...................69.Complete.trol.NaI..............49.5.3.Electronic.state.ob.jectiv7eecto.p.erties:.rational.in.elds.7.1.ciation.a.electric.................81.The.del........50.5.4.Energy.ob.jectiv.e.including.rotation..7.1.2.endular...........................7.1.3.tum..50.5.5.Orien.tation.ob.jectiv.e..........7.1.4.e.ectroscop.....................7.2.-.rotational.of..........51.6.Laser.control98ofFixedthetationNaI.molecule.53.6.1.Heating.and.co.oling.within.an.electronic.state..7.2.2.dynamics.................7.2.3.dynamics56a6.1.1eldHeating......107.Molecular.olarizabilit.and.tation...................Contents183IriangularI.I.8SummaLaser.controledof.a.molecula.radiabaticmotoofr.117dump8.1.Mo.del.and.con.trol.sc.hemeendix...209.......143.induced.10.1.........c.................Zusammenfassung.b118.8.2.GroundofstateTheastationinitial.state..........Molecula.ro.y.pulses.del.................10.2........120.8.3.Arbitrary.initial.state10.3...............158.171.A.A.1.w.diabatic.......185.205.Vitae.role.orien..........123.8.4.Dressed.initial.state.in.a.static.eld10.r.p.cesses.b.chirp.laser.147.Mo....................125.9.Photoasso.ciation.131.9.1.Mo.del149andLinearconhirptrol.sc.hemes..........................150.T.phase................131.9.2.Fixed.orien.tation:.s-w.a11vrye12scattering177.App.183.Change.et.een.and.picture.............Bibliography.List.publications.Danksagung.Curriculum1359.3cIntelehensible.ligenceverythingeusisehendtheincability?mileoftotheomprintelthatleisctomprthatCharlesalPicardlows