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Publié par | philipps-universitat_marburg |
Publié le | 01 janvier 2006 |
Nombre de lectures | 17 |
Langue | English |
Poids de l'ouvrage | 5 Mo |
Extrait
Metal Complexes with Non-innocent
N-donor Ligands: Molecular and
Electronic Structures, Reactivity, and
Application
Dissertation
zur
Erlangung des Doktorgrades
der Naturwissenschaften
(Dr. rer. nat.)
dem
Fachbereich Chemie
der Philipps-Universität Marburg
vorgelegt von
Marat M. Khusniyarov
aus
Petropawlowsk-Kamtschatskiy
Russland
Marburg an der Lahn
2006Vom Fachbereich Chemie
der Philipps-Universität Marburg als Dissertation am 09.06.2006 angenommen.
Erstgutachter: Prof. Dr. J. Sundermeyer
Zweitgutachter: Prof. Dr. M. Bröring
Tag der mündlichen Prüfung am 30.06.2006to my wife MariaChemistry is just Physics
of valence electronsArticles published:
M. M. Khusniyarov, K. Harms, J. Sundermeyer;
New Highly Fluorinated Phenazine Derivatives: Correlation between Crystal Structure and
NMR Spectroscopy.
J. Fluorine Chem. 2006, 127, 200– 204.
M. M. Khusniyarov, K. Harms, O. Burghaus, J. Sundermeyer;
Molecular and Electronic Structures of Homoleptic Nickel and Cobalt Complexes with
Non-innocent Bulky Diimine Ligands Derived from Fluorinated 1,4-Diaza-1,3-butadien
(DAD) and Bis(arylimino)acenaphthene (BIAN).
Eur. J. Inorg. Chem. 2006, article online.
M. M. Khusniyarov, K. Harms, J. Sundermeyer, B. Sarkar, W. Kaim, J. van Slageren, C.
Duboc, J. Fiedler;
A Series of Metal Complexes with the Non-Innocent N,N’-Bis(pentafluorophenyl)-o-
phenylenediamine: Twisted Geometry as a Tuner for Electronic Structure.
Manuscript in preparation.
Report:
M. M. Khusniyarov;
Late Transition Metal Complexes with Non-innocent Nitrogen Ligands.
"Aktuelle Themen aus der Anorganischen Chemie", Fachbereich Chemie der Philipps-
thUniversität, Marburg, 9 February, 2006.
IAcknowledgements
I would like to acknowledge everyone who extended their support and help during the course of this
work. My deep sense of gratitude goes to:
Prof. Dr. Jörg Sundermeyer for a great opportunity to perform my PhD work in his
research group and for this interesting research topic.
Dr. Klaus Harms for all X-ray structures he determined.
Gertraud Geiseler for her patience by searching for good crystals among dark powder in
dark solutions.
Dr. Xiulan Xie for her interesting NMR lectures and for her help by my first steps on
working with NMR spectrometers.
The whole NMR department for measurements of NMR spectra on high frequency
spectrometers and for assistance by my independent measurements.
Dr. Olaf Burghaus for recording of EPR spectra, their simulation, and interesting
discussions about spins, ZFS, etc.
P. Clemens for SQUID measurements and great interest in magnetic properties of my
complexes.
Dr. Steinbach for his understanding of my problems regarding mass spectrometry and
help on working with MALDI spectrometer.
The whole mass department for recording of numerous mass spectra for me.
Prof. Dr. Martin Bröring for opportunity to perform UV-vis measurements at his research
group and for his consent to be the second referee for this work.
Prof. Dr. Wolfgang Kaim and Dr. Biprajit Sarkar (Stuttgart University) for their interest
in part of the present work and fruitful collaboration (physicochemical investigation of
complexes in Chapter I).
Alex Petrov for his introduction of synthetic chemistry to me and interesting discussions
about chemistry and more, as well as for a nice time in and outside the laboratory.
Dr. Alexey Merkoulov for his fruitful discussions concerning physical chemistry and
spectroscopy.
Irene Barth for her assistance in searching for every possible glasses, equipments, etc. in
our big laboratory.
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